How To Make Chocolate

Chocolate liquor is blended with the butter in varying quantities to make different types of chocolate or couvertures. The basic blends of ingredients, in order of highest quantity of cocoa liquor first, are as follows. (Note that since U.S. chocolates have a lower percentage requirement of cocoa liquor for dark chocolate, some dark chocolate may have sugar as the top ingredient.)

1. Plain dark chocolate: sugar, cocoa butter, cocoa liquor, and (sometimes) vanilla
2. Milk chocolate: sugar, cocoa butter, cocoa liquor, milk or milk powder, and vanilla
3. White chocolate: sugar, cocoa butter, milk or milk powder, and vanilla

Usually, an emulsifying agent such as soya lecithin is added, though a few manufacturers prefer to exclude this ingredient for purity reasons and to remain GMO-free (Soya is a heavily genetically modified crop), sometimes at the cost of a perfectly smooth texture. Some manufacturers are now using PGPR, an artificial emulsifier derived from castor oil that allows them to reduce the amount of cocoa butter while maintaining the same mouthfeel.

The texture is also heavily influenced by processing, specifically conching (see below). The more expensive chocolates tend to be processed longer and thus have a smoother texture and "feel" on the tongue, regardless of whether emulsifying agents are added.

Different manufacturers develop their own "signature" blends based on the above formulas but varying proportions of the different constituents are used.

The finest plain dark chocolate couvertures contain at least 70% cocoa (solids + butter), whereas milk chocolate usually contains up to 50%. High-quality white chocolate couvertures contain only about 33% cocoa. Inferior and mass-produced chocolate contains much less cocoa (as low as 7% in many cases) and fats other than cocoa butter. Some chocolate makers opine that these "brand name" milk chocolate products can not be classed as couvertures, or even as chocolate, because of the low or virtually non-existent cocoa content.

Conching

The penultimate process is called conching. A conche is a container filled with metal beads, which act as grinders. The refined and blended chocolate mass is kept liquid by frictional heat. The conching process produces cocoa and sugar particles smaller than the tongue can detect; hence the smooth feel in the mouth. The length of the conching process determines the final smoothness and quality of the chocolate. High-quality chocolate is conched for about 72 hours, lesser grades about four to six hours. After the process is complete, the chocolate mass is stored in tanks heated to approximately 45–50 °C (113–122 °F) until final processing.

Tempering The final process is called tempering. Uncontrolled crystallization of cocoa butter typically results in crystals of varying size, some or all large enough to be clearly seen with the naked eye. This causes the surface of the chocolate to appear mottled and matte, and causes the chocolate to crumble rather than snap when broken. The uniform sheen and crisp bite of properly processed chocolate are the result of consistently small cocoa butter crystals produced by the tempering process.

The fats in cocoa butter can crystallize in six different forms (polymorphous crystallization). The primary purpose of tempering is to assure that only the best form is present. The six different crystal forms have different properties.

Making good chocolate is about forming the most of the type V crystals. This provides the best appearance and mouth feel and creates the most stable crystals so the texture and appearance will not degrade over time. To accomplish this, the temperature is carefully manipulated during the crystallization.

The chocolate is first heated to 45°C (113°F) to melt all six forms of crystals. Then the chocolate is cooled to about 27°C (80°F), which will allow crystal types IV and V to form (VI takes too long to form). At this temperature, the chocolate is agitated to create many small crystal "seeds" which will serve as nuclei to create small crystals in the chocolate. The chocolate is then heated to about 31°C (88°F) to eliminate any type IV crystals, leaving just the type V. After this point, any excessive heating of the chocolate will destroy the temper and this process will have to be repeated.

Two classic ways of tempering chocolate are: 1. Working the melted chocolate on a heat-absorbing surface, such as a stone slab, until thickening indicates the presence of sufficient crystal "seeds"; the chocolate is then gently warmed to working temperature.
2. Stirring solid chocolate into melted chocolate to "inoculate" the liquid chocolate with crystals (this method uses the already formed crystal of the solid chocolate to "seed" the melted chocolate).

No more than a pound at a time should ever be tempered, and tempering shouldn't be attempted when the air temperature is over 24°C (75 degrees Fahrenheit). A third, more modern tempering method involves using a microwave oven. A pound of coarsely chopped chocolate should be placed in an open, microwave-safe glass or ceramic container. The chocolate should be microwaved at full power for one minute and then stirred briefly. Continue to microwave at full power in ten-second increments until the chocolate is about 2/3 melted and 1/3 solid or lumpy. Then stir briskly until all the chocolate is completely melted and smooth.

Using a candy thermometer, the temperature must be tested as follows for the different types of chocolate:

  • 31.1 to 32.7 degrees Celsius (88 to 91 degrees Fahrenheit) for dark chocolate, the generic term for semisweet chocolate or bittersweet chocolate.
  • 28.9 to 30.5 degrees Celsius (84 to 87 degrees Fahrenheit) for milk chocolate or white chocolate.

Storing

Chocolate is very sensitive to temperature and humidity. Ideal storage temperatures are between 15 and 17 degrees Celsius (59 to 63 degrees Fahrenheit), with a relative humidity of less than 50%. Chocolate should be stored away from other foods as it can absorb different aromas. Ideally, chocolates are packed or wrapped and then placed in proper storage areas with the correct humidity and temperatures. Additionally chocolate should be stored in a dark place or protected from light by wrapping paper. Sunlight could warm up the surface of the chocolate and cause it to get 'grey', this being the cocoa butter crystals forming on the surface of it. It will also slightly change the tasting sensation, because of the different stage that the cocoa butter is in then.

Courtesy of Wikipedia